Bis[2-(1H-benzimidazol-2-yl)phenolato]dimethanolmanganese(III) chloride
نویسندگان
چکیده
In the title compound, [Mn(C(13)H(9)N(2)O)(2)(CH(3)OH)(2)]Cl, the Mn(III) atom (site symmetry ) is coordinated by two N,O-bidentate 2-(1H-benzimidazol-2-yl)phenolate ligands and two methanol mol-ecules, to generate a distorted trans-MnN(2)O(4) octa-hedral geometry for the metal ion. The dihedral angle between the aromatic ring systems in the ligand is 16.0 (3)°. In the crystal structure, the complex cations and chloride anions are linked by O-H⋯Cl and N-H⋯Cl hydrogen bonds. The chloride ion lies on a crystallographic twofold axis.
منابع مشابه
Bis[2-(1H-benzimidazol-2-yl)phenolato-κ2 N 3,O]cobalt(II) dimethylformamide disolvate
In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry. The dimethyl-formamide solvent mol-ecules are found inside a two-dimensional network structure formed by inter-molecular N-H⋯O hydrogen bonds linki...
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